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Co3O4/Co-N-C modified ketjenblack carbon as an advanced electrocatalyst for Al-air batteries

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成果类型:
期刊论文
作者:
Li, Jingsha;Zhou, Zhi;Liu, Kun;Li, Fuzhi;Peng, Zhiguang;...
通讯作者:
Tang, Yougen;Wang, Haiyan
作者机构:
[Li, Fuzhi; Liu, Kun; Wang, Haiyan; Peng, Zhiguang; Li, Jingsha; Tang, Yougen; Wang, HY] Cent S Univ, Coll Chem & Chem Engn, Changsha 410083, Hunan, Peoples R China.
[Zhou, Zhi] Hunan Agr Univ, Coll Sci, Changsha 410128, Hunan, Peoples R China.
通讯机构:
[Tang, YG; Wang, HY] C
Cent S Univ, Coll Chem & Chem Engn, Changsha 410083, Hunan, Peoples R China.
语种:
英文
关键词:
Ketjenblack carbon;Cobalt oxide;Oxygen reduction reaction;Catalyst;Al-air batteries
期刊:
Journal of Power Sources
ISSN:
0378-7753
年:
2017
卷:
343
期:
Mar.1
页码:
30-38
基金类别:
National Nature Science Foundations of ChinaNational Natural Science Foundation of China (NSFC) [21271187, 21571189, 21671200]; Fundamental Research Funds for the Central Universities of Central South University [502210006]; Open End Fund for Valuable and Precision Instruments of Central South University [CSUZC201622]
机构署名:
本校为其他机构
院系归属:
理学院
摘要:
Nitrogen-doped carbon materials containing non-precious metal (TM-N-C) and Co-based oxides have been extensively investigated as promising catalysts for oxygen reduction reaction (ORR). Herein, we report a novel Co3O4/Co-N-C modified ketjenblack carbon (KB) catalyst via a one-pot and scalable pyrolysis process using cheap melamine, cobalt acetate tetrahydrate and KB as raw materials. Owing to the high specific surface area and good electrical conductivity, this KB-based catalyst exhibits remarkable catalytic activity with a half-wave potential of 0.798 V (vs RHE) and a limiting current density...

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