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Colorimetric and visual determination of acrylamide via acrylamide-mediated polymerization of acrylamide-functionalized gold nanoparticles

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成果类型:
期刊论文
作者:
Shi, Xingbo*;Lu, Dai;Wang, Zimeng;Zhang, Dong;Gao, Wenli;...
通讯作者:
Shi, Xingbo;Deng, Jiehong;Guo, Shiyin
作者机构:
[Deng, Jiehong; Shi, Xingbo; Gao, Wenli; Zhang, Dong; Lu, Dai; Zhang, Chunyan; Shi, XB; Deng, JH; Guo, Shiyin; Wang, Zimeng] Hunan Agr Univ, Coll Food Sci & Technol, Hunan Prov Key Lab Food Sci & Biotechnol, Changsha 410128, Hunan, Peoples R China.
[Shi, Xingbo] Hunan Univ, State Key Lab Chemo Biosensing & Chemometr, Changsha 410082, Hunan, Peoples R China.
通讯机构:
[Shi, XB; Deng, JH; Guo, SY; Shi, Xingbo] H
Hunan Agr Univ, Coll Food Sci & Technol, Hunan Prov Key Lab Food Sci & Biotechnol, Changsha 410128, Hunan, Peoples R China.
Hunan Univ, State Key Lab Chemo Biosensing & Chemometr, Changsha 410082, Hunan, Peoples R China.
语种:
英文
关键词:
Colorimetry;Polymerization;Carbon-carbon double bonds;Thermally processed food;Food safety;Vinyl compounds;Photo-initiator
期刊:
Microchimica Acta
ISSN:
0026-3672
年:
2018
卷:
185
期:
11
页码:
1-9
基金类别:
Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [31301484]; Natural Science Foundation of Hunan ProvinceNatural Science Foundation of Hunan Province [2015JJ3082]; Excellent Youth Foundation of Education Department of Hunan Province [17B124]; Open Foundation of State Key Laboratory of Chemo/Biosensing and Chemometrics [Z2015025]
机构署名:
本校为第一且通讯机构
院系归属:
食品科学技术学院
摘要:
A colorimetric assay is described for acrylamide (AA). It is based on color changes induced by an increase in the distance between gold nanoparticles (AuNPs) that is caused by AA copolymerization. First, AuNPs were modified with a thiolated propylene amide poly(ethylene glycol) that also contains the AA functionality. The carbon-carbon double bonds on the modified AuNPs can be polymerized under the catalysis of a photoinitiator and under UV irradiation. This results in the aggregation of the AuNPs and in a color change from red to gray. In the ...

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