Aniline ortho C−H Sulfuration/Cyclization with Elemental Sulfur for Efficient Synthesis of 2-Substituted Benzothiazoles under Metal-Free Conditions

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成果类型：

期刊论文

作者：

Jiang, Jingjing;Li, Guozheng;Zhang, Feng*;Xie, Hao;Deng, Guo-Jun*

通讯作者：

Zhang, Feng;Deng, Guo-Jun

作者机构：

[Zhang, Feng; Deng, GJ; Xie, Hao; Li, Guozheng; Jiang, Jingjing; Deng, Guo-Jun] Xiangtan Univ, Key Lab Green Organ Synth & Applicat Hunan Prov, Key Lab Environm Friendly Chem & Applicat, Minist Educ,Coll Chem, Xiangtan 411105, Peoples R China.

[Zhang, Feng] Hunan Agr Univ, Coll Sci, Changsha 410128, Hunan, Peoples R China.

通讯机构：

[Zhang, F; Deng, GJ] X

[Zhang, Feng] H

Xiangtan Univ, Key Lab Green Organ Synth & Applicat Hunan Prov, Key Lab Environm Friendly Chem & Applicat, Minist Educ,Coll Chem, Xiangtan 411105, Peoples R China.

Hunan Agr Univ, Coll Sci, Changsha 410128, Hunan, Peoples R China.

语种：

英文

关键词：

2-substituted benzothiazoles;aromatic amines;elemental sulfur;metal-free

期刊：

ADVANCED SYNTHESIS & CATALYSIS

ISSN：

1615-4150

年：

2018

卷：

360

期：

页码：

1622-1627

DOI：

10.1002/adsc.201701560

基金类别：

National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21572194, 21502160, 21372187]; Collaborative Innovation Center of New Chemical Technologies for Environmental Benignity and Efficient Resource Utilization; Hunan Provincial Innovative Foundation for Postgraduate [CX2017B293]

机构署名：

本校为通讯机构

院系归属：

理学院

摘要：

A three-component synthesis of 2-substituted benzothiazoles from aryl amines, elemental sulfur and styrenes or aryl acetylenes in 1-methylpyrrolidin-2-one (NMP) is described. Two C−S and one C−N bonds were selectively formed in one-pot under metal-free conditions. (Figure presented.). © 2018 Wile...

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Aniline ortho C−H Sulfuration/Cyclization with Elemental Sulfur for Efficient Synthesis of 2-Substituted Benzothiazoles under Metal-Free Conditions

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