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Electrochemical behavior and voltammetric determination of vanillin based on an acetylene black paste electrode modified with graphene–polyvinylpyrrolidone composite film

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成果类型:
期刊论文
作者:
Deng, Peihong*;Xu, Zhifeng;Zeng, Rongying;Ding, Chunxia
通讯作者:
Deng, Peihong
作者机构:
[Deng, Peihong; Xu, Zhifeng; Zeng, Rongying] Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Peoples R China.
[Zeng, Rongying] Hunan Agr Univ, Coll Resource & Environm, Changsha 410128, Hunan, Peoples R China.
[Ding, Chunxia] Hunan Agr Univ, Coll Sci, Changsha 410128, Hunan, Peoples R China.
通讯机构:
[Deng, Peihong] H
Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Peoples R China.
语种:
英文
关键词:
Electrochemical behavior;Electrochemical sensor;Graphene-polyvinylpyrrolidone composite film;Vanillin;Voltammetric determination
期刊:
Food Chemistry
ISSN:
0308-8146
年:
2015
卷:
180
页码:
156-163
基金类别:
This work was supported by the Project of National Natural Science Foundation of China (Nos. 21105024 and 21472038 ), the Project of Science and Technology Department of Hunan Province ( 2014SK3178 ) and the Key Discipline Project of Hunan Province .
机构署名:
本校为其他机构
院系归属:
资源环境学院
理学院
摘要:
The graphene-polyvinylpyrrolidone composite film modified acetylene black paste electrode (GR-PVP/ABPE) was fabricated and used to determine vanillin. In 0.1 M H3PO4 solution, the oxidation peak current of vanillin increased significantly at GR-PVP/ABPE compared with bare ABPE, PVP/ABPE and GR/ABPE. The oxidation mechanism was discussed. The experimental conditions that exert influence on the voltammetric determination of vanillin, such as supporting electrolytes, pH values, accumulation potential and accumulation time, were optimized. Besides,...

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