The Duffing equation with even-odd asymmetrical nonlinear-restoring force and one external forcing is investigated. The conditions of existence of primary resonance, second-order, third-order subharmonics, morder subharmonics and chaos are given by using the second-averaging method, the Melnikov method and bifurcation theory. Numerical simulations including bifurcation diagram, bifurcation surfaces and phase portraits show the consistence with the theoretical analysis. The numerical results also exhibit new dynamical behaviors including onset of chaos, chaos suddenly disappearing to periodic o...