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Simultaneous determination of hydroquinone, catechol and resorcinol with high selectivity based on hollow nitrogen-doped mesoporous carbon spheres decorated graphene

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成果类型:
期刊论文
作者:
Peng, Chang;Li, Zefan;Zhang, Xuemei;Zhou, Suya;Zhang, Wei;...
通讯作者:
Liu, Xiaoying;Zhao, Peng
作者机构:
[Liu, Xiaoying; Peng, Chang; Zhang, Wei; Zhou, Suya; Zhang, Xuemei; Li, Zefan] Hunan Agr Univ, Coll Sci, Changsha 410128, Hunan, Peoples R China.
[Zhao, Peng] Southern Med Univ, Guangzhou Key Lab Drug Res Emerging Virus Prevent, Sch Pharmaceut Sci, Guangdong Prov Key Lab New Drug Screening, Guangzhou 510515, Guangdong, Peoples R China.
通讯机构:
[Liu, Xiaoying] H
[Zhao, Peng] S
Hunan Agr Univ, Coll Sci, Changsha 410128, Hunan, Peoples R China.
Southern Med Univ, Guangzhou Key Lab Drug Res Emerging Virus Prevent, Sch Pharmaceut Sci, Guangdong Prov Key Lab New Drug Screening, Guangzhou 510515, Guangdong, Peoples R China.
语种:
英文
关键词:
Catalyst activity;Doping (additives);Graphene;Mesoporous materials;Nitrogen;Spheres;Electrocatalytic activity;High selectivity;High surface area;Linear response;Mesoporous carbon;Nitrogen-doped mesoporous carbons;Simultaneous determinations;Tap-water samples;Phenols
期刊:
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
ISSN:
0013-4651
年:
2018
卷:
165
期:
5
页码:
B212-B219
基金类别:
This work was financially supported by the National Natural Science Foundation of China (Nos. 21606081, 21605077), Opening Fund of Key Laboratory of Chemical Biology and Traditional Chinese Medicine Research (Hunan Normal University) Ministry of Education (KLCBTCMR2011-08), Introduce Talents Fund of Hunan Agricultural University (13YJ01). 1College of Science, Hunan Agricultural University, Changsha 410128, People’s Republic of China 2Guangdong Provincial Key Laboratory of New Drug Screening, Guangzhou Key Laboratory of Drug Research for Emerging Virus Prevention and Treatment, School of Pharmaceutical Sciences, Southern Medical University, Guangzhou 510515, People’s Republic of China
机构署名:
本校为第一且通讯机构
院系归属:
理学院
摘要:
For the first time, we have synthesized hollow nitrogen-doped mesoporous carbon spheres decorated graphene (NMC-G) and applied it in the simultaneous determination of hydroquinone (HQ) resorcinol (RC) and catechol (CC) in real samples. In the composite of NMC-G, hollow mesoporous carbon spheres possess high surface area and graphene have shown high electro-catalytic activity to many electroactive substances. As a result, the oxidation overpotentials of HQ, RC and CC decreased and the potential separations were 0.38, 0.49 and 0.11 V for CC and R...

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