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Fabrication of Atrazine Molecularly Imprinted Polymer Microsphere by Two Step Seed Swelling Polymerization Method

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成果类型:
期刊论文
作者:
Chen, Jun;Bai, Lianyang*;Zhang, Yijun;Chen, Na;Zhang, Yuping
通讯作者:
Bai, Lianyang
作者机构:
[Chen, Jun; Bai, Lianyang] Hunan Agr Univ, Pesticide Res Inst, Changsha 410128, Hunan, Peoples R China.
[Zhang, Yuping; Zhang, Yijun; Chen, Na; Chen, Jun] Henan Inst Sci & Technol, Xinxiang 453003, Peoples R China.
[Bai, Lianyang] Hunan Univ Humanities Sci & Technol, Loudi 417000, Peoples R China.
通讯机构:
[Bai, Lianyang] H
Hunan Agr Univ, Pesticide Res Inst, Changsha 410128, Hunan, Peoples R China.
语种:
英文
关键词:
Seed swelling;Molecular imprinting polymer microsphere;Binding capacity;Atrazine
期刊:
Journal of the Chinese Chemical Society
ISSN:
0009-4536
年:
2012
卷:
59
期:
12
页码:
1493-1499
基金类别:
Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education MinistryScientific Research Foundation for the Returned Overseas Chinese Scholars; National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [30070506, 30771436]
机构署名:
本校为第一且通讯机构
院系归属:
植物保护学院
摘要:
Atrazine molecularly imprinted polymer microspheres (MIPMs) were fabricated by two step seed swelling polymerization method, using atrazine as a template molecule, methacrylic acid (MAA) as a functional monomer, ethylene glycol dimethacrylate (EDMA) as a crosslinking agent and toluene/dodecanol as a porogenic agent and a series of MIPMs with even particle size of 3-5 μm and good dispersivity could be obtained under the optimal condition. Equilibrium binding experiments were comparably studied about the binding capacity of the resulted polymers...

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