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A flexible polycation-type anion-dominated conducting polymer as potential all-solid-state supercapacitor film electrolyte

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成果类型:
期刊论文
作者:
Yang, Yahui;Cao, Bianmei;Li, Hang;Liu, Hongtao*
通讯作者:
Liu, Hongtao
作者机构:
[Li, Hang; Yang, Yahui] Hunan Agr Univ, Coll Resources & Environm, Changsha 410128, Hunan, Peoples R China.
[Cao, Bianmei; Liu, Hongtao] Cent S Univ, Coll Chem & Chem Engn, Changsha 410083, Hunan, Peoples R China.
[Liu, Hongtao] Hunan Prov Key Lab Efficient & Clean Utilizat Man, Changsha 410083, Hunan, Peoples R China.
通讯机构:
[Liu, Hongtao] C
Cent S Univ, Coll Chem & Chem Engn, Changsha 410083, Hunan, Peoples R China.
语种:
英文
关键词:
All-solid-state supercapacitor;Polycation-type conducting copolymer;Solid polymer electrolyte
期刊:
Chemical Engineering Journal
ISSN:
1385-8947
年:
2017
卷:
330
页码:
753-756
基金类别:
The financial support from the National Natural Science Foundation of China (no. 21471054) and the Hunan provincial S&T plan of China (no. 2016TP1007, 2014FJ2007) are gratefully acknowledged.
机构署名:
本校为第一机构
院系归属:
资源环境学院
摘要:
Cation-polymerized ionic liquids and non-ionic polymer monomers can be facile to chain into performance-enhanced conducting copolymers in combination with their respective features. A novel highly-flexible Br-based polycationic conducting copolymer is presented that shows both wide electrochemical window (6.0 V) and high ionic conductivity (2.04 × 10−6 S·cm−1 at 25 °C, 3.09 × 10−4 S·cm−1 at 60 °C), capable of potential solid polymer electrolyte. A 4.2 V flexible all-solid-state C/C supercapacitor is evaluated by using the poly(VAc-co-...

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