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Highly Thermal Conductive Separator with In-Built Phosphorus Stabilizer for Superior Ni-Rich Cathode Based Lithium Metal Batteries

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成果类型:
期刊论文
作者:
Zuo, Lan-Lan;Ma, Qiang;Li, Shi-Cai;Lin, Ben-Cai;Fan, Min;...
通讯作者:
Wu, Xiong-Wei;Zeng, Xian-Xiang;Guo, Yu-Guo
作者机构:
[Zuo, Lan-Lan; Ma, Qiang; Wu, Xiong-Wei; Wu, XW; Zeng, Xian-Xiang] Hunan Agr Univ, Sch Chem & Mat Sci, Changsha 410128, Hunan, Peoples R China.
[Li, Shi-Cai] Shenzhen BYD Lithium Battery Co Ltd, Shenzhen 518000, Guangdong, Peoples R China.
[Lin, Ben-Cai] Changzhou Univ, Sch Mat Sci & Engn, Jiangsu Collaborat Innovat Ctr Photovolat Sci & E, Changzhou 213164, Jiangsu, Peoples R China.
[Fan, Min; Meng, Qing-Hai; Guo, Yu-Guo] Chinese Acad Sci, Inst Chem, CAS Res Educ Ctr Excellence Mol Sci, CAS Key Lab Mol Nanostruct & Nanotechnol, Beijing 100190, Peoples R China.
[Fan, Min; Guo, Yu-Guo] Univ Chinese Acad Sci UCAS, Beijing 100049, Peoples R China.
通讯机构:
[Wu, XW; Zeng, XX] H
[Guo, Yu-Guo] C
[Guo, Yu-Guo] U
Hunan Agr Univ, Sch Chem & Mat Sci, Changsha 410128, Hunan, Peoples R China.
Chinese Acad Sci, Inst Chem, CAS Res Educ Ctr Excellence Mol Sci, CAS Key Lab Mol Nanostruct & Nanotechnol, Beijing 100190, Peoples R China.
语种:
英文
关键词:
dendrites;lithium metal batteries;nickel-rich cathodes;separators;thermal conductivity
期刊:
Advanced Energy Materials
ISSN:
1614-6832
年:
2021
卷:
11
期:
3
页码:
2003285-
基金类别:
This work was supported by the National Key R&D Program of China (Grant No. 2016YFA0202500), the National Natural Science Foundation of China (Grant Nos. 51803054, 51772093, 21773264), the Natural Science Foundation of Hunan province (Grant Nos. 2019JJ20010, 2020JJ3022, 2019JJ50223), the Double First-Class Construction Project of Hunan Agricultural University (Grant No. SYL201802008), the Outstanding Youth Foundation from Education Department of Hunan Province (Grant No. 19B270) and Open Project of Jiangsu Province State Key Laboratory of Photovoltaic Science and Technology (Grant No. SKLPST202004).
机构署名:
本校为第一且通讯机构
摘要:
The movement toward cobalt-free cathode materials has served as a motivation for increased research in layered nickel-rich cathodes for next generation metal batteries. Unfortunately, Ni-rich cathode materials suffer from low capacity retention and poor thermal stability due to phase transition that results in issues such as the oxygen evolution reaction, hindering its extensive implementation. Herein, highly pliable separators with a 3D porous structure are prepared via a facile phase-inversion method from an inorganic phosphorus-based flame r...

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