Concentration levels of Cd,Cr,As,Ni,Pb,Zn,Cu and Mn in the atomspheric TSP and exhaust gas of a Pb-Zn smelting enterprise were monitored in a typical Pb-Zn-Mn smelting area in Hunan. Enrichment factor,correlation and principal component analysis were used to study the relationship between the content of heavy metal in the exhaust gas and that in the atmospheric TSP. The US Environmental Protection Agency (USEPA) human exposure risk assessment model was adopted to conduct the health risk assessment. Results showed that mean mass concentrations i...