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Crystal structure and luminescence properties of the blue-green-emitting Ba9(Lu, Y)2Si6O24:Ce3 + phosphor

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成果类型:
期刊论文
作者:
Xu, Huawei*;Zhou, Zhi*;Liu, Yongfu*;Liu, Qunxing;He, Zhiyuan;...
通讯作者:
Xu, Huawei;Zhou, Zhi;Liu, Yongfu
作者机构:
[Liu, Qunxing; Wang, Shen; Xu, Huawei; He, Zhiyuan; Huang, Linyi] Qual Inspect & Testing Ctr, Res Inst MIIT 5, 110 Dongguan Zhuang Rd, Guangzhou 510610, Guangdong, Peoples R China.
[Zhou, Zhi] Hunan Agr Univ, Coll Sci, 1 Nongda Rd, Changsha 410128, Hunan, Peoples R China.
[Liu, Yongfu] Chinese Acad Sci, NIMTE, 1219 Western Zhongguan Rd, Ningbo 315201, Zhejiang, Peoples R China.
[Zhu, Hongbo] Chinese Acad Sci, Changchun Inst Opt Fine Mech & Phys, 3888 Nanhu Rd, Changchun 130033, Peoples R China.
通讯机构:
[Xu, Huawei] Q
[Zhou, Zhi] H
[Liu, Yongfu] C
Qual Inspect & Testing Ctr, Res Inst MIIT 5, 110 Dongguan Zhuang Rd, Guangzhou 510610, Guangdong, Peoples R China.
Hunan Agr Univ, Coll Sci, 1 Nongda Rd, Changsha 410128, Hunan, Peoples R China.
语种:
英文
关键词:
Crystal structure;Light emitting diodes;Luminescence;Phosphors;Solid state reactions;Thermodynamic stability;Blue-green phosphor;Ce 3+;Ce3 + luminescence;Crystals structures;Green phosphor;Luminescence properties;Near ultraviolet;Structure property;Synthesised;White LED's;Silicates;cerium;luminescent agent;lutetium;chemistry;color;crystallization;luminescence;powder;X ray diffraction;Cerium;Color;Crystallization;Luminescent Agents;Luminescent Measurements;Lutetium;Powders;X-Ray Diffraction
期刊:
LUMINESCENCE
ISSN:
1522-7235
年:
2017
卷:
32
期:
5
页码:
812-816
基金类别:
This work is financially supported by the National High Technology Research and Development Program of China (863 Program) (2015AA03A101), the National Natural Science Foundation of China (U1201254, 11404351, 61306059), and the Science and Technology Planning Project of Guangdong Province (2014B010122005, 2014B010122001, 2015B010114002, 2015B010133001).
机构署名:
本校为通讯机构
院系归属:
理学院
摘要:
Samples of the Ba9(Lu2-xYx)Si6O24:Ce3 + (x=0–2) blue-green phosphors were synthesized by solid-state reactions. All the samples exhibited a rhombohedral crystal structure. As the Y3 + concentration increased, the diffraction peaks shifted to the small angle region and the lattice parameters increased due to the larger ionic radius of Y3 + (r=0.900Å) compared with that of Lu3 + (r=0.861Å). Under 400nm excitation, samples exhibited strong blue-green emissions around 490nm. The emission bands had a slight blue shift that resulted from weak crys...

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