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E-Selective synthesis of vinyl sulfones via silver-catalyzed sulfonylation of styrenes

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成果类型:
期刊论文
作者:
Gui, Qingwen;Han, Kang;Liu, Zhuoliang;Su, Zhaohong;He, Xiaoli;...
通讯作者:
Jiang, Hongmei;Li, Yangyan
作者机构:
[Han, Kang; Su, Zhaohong; Tian, Bufan; Gui, Qingwen; Jiang, Hongmei; He, Xiaoli] Hunan Agr Univ, Coll Sci, Changsha 410128, Hunan, Peoples R China.
[Liu, Zhuoliang] Natl Univ Def Technol, Coll Liberal Arts & Sci, Changsha 410073, Hunan, Peoples R China.
[Li, Yangyan] Hunan Univ Sci & Engn, Coll Chem & Bioengn, Yongzhou 425199, Peoples R China.
通讯机构:
[Jiang, Hongmei; Li, Yangyan] H
Hunan Agr Univ, Coll Sci, Changsha 410128, Hunan, Peoples R China.
Hunan Univ Sci & Engn, Coll Chem & Bioengn, Yongzhou 425199, Peoples R China.
语种:
英文
关键词:
Chemical bonds;Silver;Styrene;Bond coupling;Selective synthesis;SIMPLE protocol;Sulfonylation;Vinyl sulfones;Catalysis
期刊:
Organic & Biomolecular Chemistry
ISSN:
1477-0520
年:
2018
卷:
16
期:
32
页码:
5748-5751
基金类别:
We thank the National Science Foundation of China (21705163). We thank the Hunan Province Science Foundation for Youths (2018JJ3215) and the Hunan Agricultural University Science Foundation for high-level personnel. We thank Mai-Jan Tom (Queens University) for help with the preparation of this manuscript.
机构署名:
本校为第一且通讯机构
院系归属:
理学院
摘要:
An efficient and highly E-selective protocol for the synthesis of vinyl sulfones is described. This simple protocol demonstrates the first synthesis of vinyl sulfones via a silver-catalyzed C-S bond coupling reaction. In addition, the success of the reaction was found to be critically dependent on the use of TEMPO as the additive....

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