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Preparation and characterisation of carbon-coated Magneli phase Ti4O7 by modified carbon-thermal reduction route

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成果类型:
期刊论文
作者:
Bao, Xinjun;Zhang, Zejie;Yi, Shijie;Yang, Qingshan;Yu, Peng;...
通讯作者:
Zhou, Debi
作者机构:
[Zhou, Debi; Yi, Shijie; Zhang, Zejie; Bao, Xinjun] Cent South Univ, Sch Chem & Chem Engn, Changsha 410083, Peoples R China.
[Yang, Qingshan] Hunan Nonferrous Met Vocat & Tech Coll, Zhuzhou 412006, Peoples R China.
[Yu, Peng] Hunan Agr Univ, Coll Sci, Changsha 410128, Peoples R China.
通讯机构:
[Zhou, Debi] C
Cent South Univ, Sch Chem & Chem Engn, Changsha 410083, Peoples R China.
语种:
英文
关键词:
mesoporous materials;carbon;titanium compounds;electrolytes;catalysis;heat treatment;reduction (chemical);scanning electron microscopy;semiconductor materials;composite materials;catalysts;oxygen;surface chemistry;high-pressure pelleted treatment;oxygen reduction reaction catalytic activity;titanium sulphate;polyvinyl alcohol;heat treatment temperature;carbon-coated Magnéli phase;carbon-thermal reduction route;Ti4O7 composite;carbonthermal reduction;hydrolysis;oxide ions;scanning electron microscopy;spherical morphology;mesopore structure;BET surface area;electrochemical stability;alkaline electrolyte;C-Ti4O7;O2
期刊:
Micro & Nano Letters
ISSN:
1750-0443
年:
2020
卷:
15
期:
14
页码:
984-987
基金类别:
Hunan Provincial Science and Technology Plan Project of China [2017TP1001]
机构署名:
本校为其他机构
院系归属:
理学院
摘要:
A carbon-coated Magnéli phase Ti4O7 composite has been successfully synthesised, via modified carbonthermal reduction of amorphous TiO2, which was prepared from hydrolysis of titanium sulphate and polyvinyl alcohol, at a relatively low temperature and fast reaction rate. Moreover, the effect of heat treatment temperature and time on the reduced phases is revealed. Despite removal of oxide ions, scanning electron microscopic images clearly show the obtained carbon-coated Ti4O7 composite retains well the spherical morphology of the precursor, an...

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