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High thermal stability and blue-violet emitting phosphor CaYAlO_4:Ti~(4+) with enhanced emission by Ca~(2+) vacancies

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成果类型:
期刊论文
作者:
Xia, Mao;Zhang, Yongli;Li, Minghui;Zhong, Yuan;Gu, Simin;...
通讯作者:
Zhou, Nan;Zhou, Zhi
作者机构:
[Xia, Mao; Zhang, Yongli; Zhong, Yuan; Zhou, Nan; Zhou, Zhi; Li, Minghui; Gu, Simin] Hunan Agr Univ, Coll Sci, Changsha 410128, Peoples R China.
[Xia, Mao; Zhang, Yongli; Zhong, Yuan; Zhou, Nan; Zhou, Zhi; Gu, Simin] Hunan Opt Agr Engn Technol Res Ctr, Changsha 410128, Peoples R China.
[Xia, Mao] Cent S Univ, State Key Lab Powder Met, Changsha 410083, Peoples R China.
通讯机构:
[Zhou, N; Zhou, Z] H
Hunan Agr Univ, Coll Sci, Changsha 410128, Peoples R China.
语种:
英文
关键词:
Aluminum compounds;Charge transfer;Crystal structure;Electron transitions;Luminescence;Phosphors;Thermodynamic stability;Titanium compounds;X ray powder diffraction;Blue-violet-emitting;Concentration quenching;Emitting phosphors;High thermal stability;Luminescence emission;Luminescent material;Luminescent property;Plant growth;Calcium compounds
期刊:
稀土学报(英文版)
ISSN:
1002-0721
年:
2020
卷:
38
期:
3
页码:
227-233
基金类别:
Foundation item: Project supported by the National Natural Science Foundation of China (21706060, 51703061, Natural Science Foundation of Hunan Province (2017JJ3103), Youth Project of Hunan Education Department (17B11l8), and Hunan Provincial Engineering Technology Research Center for Optical Agriculture (2018TP2003).
机构署名:
本校为第一且通讯机构
院系归属:
理学院
摘要:
Blue-violet light can not only enhance the total content of biomass and glucoside but also enrich the taste of the fruit. Thus, it is meaningful to study the blue-violet luminescent materials for plant cultivation. In this study, titanium (IV) -activated CaYAlO4 (CYAO) phosphors were synthesized by conventional high-temperature solid–state reaction. X-ray powder diffraction was employed to analyze the crystal-structure of CYAO. It is found that the doped Ti4+ ions do not change obviously the crystal structure of phosphors. Upon 246 nm excitati...

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