Electron transfer processes associated with structural Fe in clay minerals

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成果类型：

期刊论文

作者：

Yu, Chenglong;Qian, Ao;Lu, Yuxi;Liao, Wenjuan;Zhang, Peng;...

通讯作者：

Yuan, SH

作者机构：

[Qian, Ao; Tong, Man; Zhang, Peng; Yu, Chenglong; Lu, Yuxi; Yuan, Songhu] China Univ Geosci, State Key Lab Biogeol & Environm Geol, Wuhan, Peoples R China.

[Liao, Wenjuan] Hunan Agr Univ, Coll Resources & Environm, Changsha, Peoples R China.

[Dong, Hailiang; Zeng, Qiang] China Univ Geosci, Ctr Geomicrobiol & Biogeochem Res, State Key Lab Biogeol & Environm Geol, Beijing, Peoples R China.

[Yuan, Songhu] China Univ Geosci, Sch Environm Studies, Hubei Key Lab Yangtze Catchment Environm Aquat Sci, Wuhan, Peoples R China.

[Yuan, Songhu] China Univ Geosci, State Key Lab Biogeol & Environm Geol, 68 Jincheng St,East Lake High Tech Dev Zone, Wuhan 430078, Peoples R China.

通讯机构：

[Yuan, SH ] C

China Univ Geosci, State Key Lab Biogeol & Environm Geol, 68 Jincheng St,East Lake High Tech Dev Zone, Wuhan 430078, Peoples R China.

语种：

英文

关键词：

Fe-bearing clay minerals;electron transfer;edge/basal surfaces;geobattery;contaminant transformation

期刊：

Critical Reviews in Environmental Science and Technology

ISSN：

1064-3389

年：

2024

卷：

期：

页码：

13-38

DOI：

10.1080/10643389.2023.2221154

基金类别：

This work was supported by the National Natural Science Foundation of China (nos. 42025703, 42107217, 42102040, and 41830862).

机构署名：

本校为其他机构

院系归属：

资源环境学院

摘要：

Fe-bearing clay minerals are widely distributed in soils, sediments, and rocks, representing a significant Fe pool in the Earth’s crust. The electron transfer (ET) from/to structural Fe in clay minerals is a crucial electron and energy flux in the natural environment, which drives numerous biogeochemical processes and contaminant transformation. Depending on the types and properties of both clay minerals and exogenous reactants as well as aqueous chemistry, the ET processes could involve interfacial ET through edge/basal planes and interior ET...

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Electron transfer processes associated with structural Fe in clay minerals

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