The cadmium (Cd) accumulates in birnessite as it forms on the surface of paddy crusts (PC). The stability of Cd-containing birnessite is influenced by environmental factors, and destabilized birnessite releases dissolved Cd. We report the effects of pH, oxalic acid, and light on the dissolution of Cd-containing birnessite. We found that at pH 4.0, with light and 0.20 mol/L oxalic acid, the ratio of dissolved Cd and manganese (Mn) peaked after 24 h at 2978.0 mu g/g and 326.8 mg/g, respectively. The three environmental factors affected the dissolution of Cd-containing birnessite in the following...
