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Thin-walled vesicular Triazole-CN-PDI with electronic n→π* excitation and directional movement for enhanced atrazine photodegradation

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成果类型:
期刊论文
作者:
Tang, Rongdi;Zeng, Hao;Gong, Daoxin;Deng, Yaocheng;Xiong, Sheng;...
通讯作者:
Gong, Daoxin(gdx4910@163.com)
作者机构:
[Tang, Rongdi; Deng, Yaocheng; Li, Ling; Gong, Daoxin; Zhou, Zhanpeng; Xiong, Sheng; Zeng, Hao] Hunan Agr Univ, Coll Resources & Environm, Changsha 410128, Peoples R China.
[Wang, Jiajia; Tang, Lin] Hunan Univ, Coll Environm Sci & Engn, Changsha 410082, Peoples R China.
[Feng, Chengyang] King Abdullah Univ Sci & Technol, KAUST Catalysis Ctr, Phys Sci & Engn Div, Thuwal 239556900, Saudi Arabia.
通讯机构:
[Daoxin Gong; Yaocheng Deng] C
College of Resources & Environment, Hunan Agricultural University, Changsha 410128, China
语种:
英文
关键词:
Atrazine degradation;Molecular modification;N→π* electron excitation;Photocatalysis;Polymeric carbon nitride
期刊:
Chemical Engineering Journal
ISSN:
1385-8947
年:
2023
卷:
451
页码:
138445
基金类别:
The study was financially supported by the National Natural Science Foundation of China (Grant No.51909089), Natural Science Foundation of Hunan Province, China (Grant No. 2020JJ5252, 2021JJ40091), China Postdoctoral Science Foundation (Grant No. 2019 M662781), Science Foundation for Young Scholars of Hunan Agricultural University (19QN35), and Hunan Provincial Innovation Foundation for Postgraduate (CX20200663).
机构署名:
本校为第一机构
院系归属:
资源环境学院
摘要:
Polymeric carbon nitride (PCN) as a competitive non-metal photocatalyst, has been widely applied in water treatment. However, the limited visible-light utilization and high photocarrier recombination rate restrict its photocatalytic efficiency. Herein, triazole and pyromellitic diimide were applied for the bimolecular decoration of polymeric carbon nitride (PCN) to fabricate TA-CN-PDI for the photodegradation of atrazine. The thin-walled vesicular morphology in TA-CN-PDI can enhance the n→π* electron excitation, and the donor-π-acceptor elec...

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