In a word, the SGC series composites anode were successfully synthesized by a FTCVD way in a FTCVD device. EDX elemental mapping and cross section SEM image of SGC granule indicates that the SGC is made up of homogeneous distribution of oxygen, carbon and silicon elements and the carbon is focusing on the external of SiO particles, which indicates that the granules are uniformly coated with carbon layer. Electrochemical tests show that the SGC-37 present a good cycle stability and rate