The gel‐like Pickering HIPEs can be more stable by using SNCs‐BSA complexes with merely 0.5% and 0.05% w/v, respectively, than applying SNCs alone. And the resulted gel‐like structure can be enhanced during pH 4.7–10. Abstract In this study, novel high internal phase emulsions (HIPEs) (φoil = 0.8) are successfully stabilized using 0.5% w/v starch nanocrystals (SNCs) and 0.05% w/v bull serum albumin (BSA) complex. For this purpose, the SNCs are made hydrophobic through modifications with different concentrations of BSA (0–0.5%) before bein...