Plasma milling modified Sb2S3-graphite nanocomposite as a highly reversible alloying-conversion anode material for lithium storage

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成果类型：

期刊论文

作者：

Liu, Yuxuan;Lu, Zhongchen*;Cui, Jie;Liu, Hui;Liu, Jun;...

通讯作者：

Hu, Renzong;Lu, Zhongchen

作者机构：

[Hu, Renzong; Zhu, Min; Liu, Yuxuan; Liu, Jun] South China Univ Technol, Sch Mat Sci & Engn, Guangdong Prov Key Lab Adv Energy Storage Mat, Guangzhou 510640, Peoples R China.

[Lu, Zhongchen] South China Univ Technol, Sch Mech & Automot Engn, Guangdong Prov Key Lab Adv Energy Storage Mat, Guangzhou 510640, Peoples R China.

[Cui, Jie] South China Univ Technol, Anal & Test Ctr, Guangzhou 510640, Peoples R China.

[Liu, Hui] Hunan Agr Univ, Coll Sci, Changsha 410128, Hunan, Peoples R China.

通讯机构：

[Hu, Renzong; Lu, Zhongchen] S

South China Univ Technol, Sch Mat Sci & Engn, Guangdong Prov Key Lab Adv Energy Storage Mat, Guangzhou 510640, Peoples R China.

South China Univ Technol, Sch Mech & Automot Engn, Guangdong Prov Key Lab Adv Energy Storage Mat, Guangzhou 510640, Peoples R China.

语种：

英文

关键词：

Antimony sulfide;Plasma milling;Conversion reactions;Reversibility

期刊：

Electrochimica Acta

ISSN：

0013-4686

年：

2019

卷：

310

页码：

26-37

DOI：

10.1016/j.electacta.2019.04.104

基金类别：

National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [51671088, 51621001, 51822104, 51831009]; Guangzhou Science and Technology Plan Projects [201707010191]

机构署名：

本校为其他机构

院系归属：

理学院

摘要：

Poor reversibility of conversion and alloying reactions for Sb2S3 limits its application as high capacity anode for rechargeable lithium storage. Herein a facile high-efficiency plasma assisted milling (P-milling) was used to create Sb2S3-C hybrid nanostructure with disk-like Sb2S3 nanograins wrapped within ultrathin graphite nanosheets. Benefiting from the high structure stability and excellent Li+ ion diffusion kinetics in the graphite wrapped Sb2S3 nanostructure, highly reversible conversion and alloying reactions are maintained throughout the long-term cycles. The Sb2S3-C nanocomposite ano...

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Plasma milling modified Sb2S3-graphite nanocomposite as a highly reversible alloying-conversion anode material for lithium storage

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