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Raising the capacity of lithium vanadium phosphate via anion and cation co-substitution

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成果类型:
期刊论文
作者:
Zeng, Xian-Xiang;Chen, Hui;Guo, Gang;Li, Sheng-Yi;Liu, Jin-Ying;...
通讯作者:
Wu, Xiong-Wei;Guo, Yu-Guo
作者机构:
[Ma, Qiang; Chen, Hui; Wu, Xiong-Wei; Liu, Jin-Ying; Guo, Gang; Zeng, Xian-Xiang] Hunan Agr Univ, Coll Sci, Changsha 410128, Peoples R China.
[Li, Sheng-Yi; Yin, Ya-Xia; Guo, Yu-Guo] Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, Lab Mol Nanostruct & Nanotechnol, Beijing 100190, Peoples R China.
[Li, Sheng-Yi; Yin, Ya-Xia; Guo, Yu-Guo] Univ Chinese Acad Sci, Beijing 100049, Peoples R China.
[Liu, Guote] Foshan Univ, Coll Elect Engn & Automat, Foshan 528225, Peoples R China.
通讯机构:
[Wu, Xiong-Wei] H
[Guo, Yu-Guo] C
[Guo, Yu-Guo] U
Hunan Agr Univ, Coll Sci, Changsha 410128, Peoples R China.
Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, Lab Mol Nanostruct & Nanotechnol, Beijing 100190, Peoples R China.
语种:
英文
关键词:
polyanion cathode;ion substitution;carbon coating;high rate;theoretical capacity
期刊:
中国科学:化学英文版
ISSN:
1674-7291
年:
2020
卷:
63
期:
2
页码:
203-207
基金类别:
supported by the Basic Science Center Project of Natural Science Foundation of China(51788104); the National Natural Science Foundation of China(51803054,51772093); the “Transformational Technologies for Clean Energy and Demonstration”,Strategic Priority Research Program of the Chinese Academy of Sciences(XDA21070300); the Natural Science Foundation of Hunan Province(2019JJ50223); “Double First-Class” School Construction Project; Outstanding Youth Fund of Hunan province(SYL201802008,2019JJ20010);
机构署名:
本校为第一且通讯机构
院系归属:
理学院
摘要:
The pursuit for batteries with high specific energy provokes the research of high-voltage/capacity cathode materials with superior stability and safety as the alternative for lithium iron phosphate. Herein, using the sol-gel method, a lithium vanadium phosphate with higher average discharge voltage (3.8 V, vs. Li~+/Li) was obtained from a single source for Mg~(2+) and Cl~- co-substitution and uniform carbon coating, and a nearly theoretical capacity (130.1 mA h g~(-1)) and outstanding rate performance (25 C) are acquired together with splendid capacity retention (80%) after 650 cycles. This wo...

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