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Adsorption of Cu2+ from aqueous solutions by Si-substituted carbonate hydroxyapatite prepared from egg-shell: kinetics, isotherms and mechanism studies

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成果类型:
期刊论文
作者:
Zeng, Rongying;Tang, Wenqing*;Liu, Xing;Ding, Chunxia;Gong, Daoxin*
通讯作者:
Gong, Daoxin;Tang, Wenqing
作者机构:
[Ding, Chunxia; Gong, Daoxin; Zeng, Rongying] Hunan Agr Univ, Coll Resources & Environm, Changsha 410128, Hunan, Peoples R China.
[Liu, Xing; Tang, Wenqing; Zeng, Rongying] Hengyang Normal Univ, Coll Chem & Mat Sci, Hengyang 421008, Peoples R China.
通讯机构:
[Gong, Daoxin; Tang, Wenqing] H
Hunan Agr Univ, Coll Resources & Environm, Changsha 410128, Hunan, Peoples R China.
Hengyang Normal Univ, Coll Chem & Mat Sci, Hengyang 421008, Peoples R China.
语种:
英文
关键词:
Adsorption;Cu;Isotherms;Kinetics;Mechanism;Si-substituted carbonate hydroxyapatite
期刊:
Desalination and Water Treatment
ISSN:
1944-3994
年:
2018
卷:
116
页码:
137-147
基金类别:
Hunan Provincial Natural Science Foundation of ChinaNatural Science Foundation of Hunan Province [13JJ9018, 2016JJ6013]; National Nature Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21603065]; Research Center of Environmental Education, Key Research Base of Philosophy & Social Sciences in Hunan Province [HJ15k01]
机构署名:
本校为第一且通讯机构
院系归属:
资源环境学院
摘要:
Si-substituted carbonate hydroxyapatite (Si-CHAP) was obtained by embedding silicate and carbonate into hydroxyapatite prepared from egg-shell via sonochemistry coprecipitation. Batch experiments were performed to investigate the effect of contact time, solution pH and temperature on the adsorption of Cu2+ by Si-CHAP. Our results showed that the maximal adsorption capacity, Qm of Cu2+ reached to 246.80 mg g–1 at pH 5.7, and at 90 min contact time under 313 K. Adsorption kinetics followed pseudo-second order. The equilibrium process fit the Lan...

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