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Natural sunlight driven degradation of tetracycline in wastewater by dual Z − scheme photocatalyst of hollow nanospherical β–In2S3 decorated g − C3N4/WO3: performance, mechanism and products toxicity

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成果类型:
期刊论文
作者:
Lu, Huamei;Li, Xueying;Jiang, Yi;Hu, Xiaolong;Zhou, Shufeng;...
通讯作者:
Zou, Dongsheng;Wu, ZB
作者机构:
[Lu, Huamei; Li, Xueying; Zou, Dongsheng; Sun, Haibo; Liang, Yunshan; Wu, Zhibin; Hu, Xiaolong; Jiang, Yi; Zhou, Shufeng; Gong, Xiaomin] Hunan Agr Univ, Coll Environm & Ecol, Changsha 410128, Peoples R China.
[Lu, Huamei; Li, Xueying; Sun, Haibo; Liang, Yunshan; Hu, Xiaolong; Wu, Zhibin; Jiang, Yi; Zhou, Shufeng; Zou, Dongsheng; Gong, Xiaomin] Key Lab Rural Ecosyst Hlth Dongting Lake Area Huna, Changsha 410128, Peoples R China.
通讯机构:
[Zou, DS; Wu, ZB ] H
Hunan Agr Univ, Coll Environm & Ecol, Changsha 410128, Peoples R China.
语种:
英文
关键词:
Dual Z-scheme;Natural photocatalysis;Antibiotic;Degradation mechanisms;Products toxicity
期刊:
Chemical Engineering Journal
ISSN:
1385-8947
年:
2023
卷:
476
页码:
146718
基金类别:
National Natural Science Foundation of China [51808215]; Provincial Natural Science Foundation of Hunan [2019JJ50253]; Hunan Provincial Key R D [2023NK2029]; Scientific and technological innovation platform and talent plan of Hunan Province [2020RC2056]; Hunan provincial special project for the construction of National Innovation Demonstration Zone of Chenzhou [2022sfq41]
机构署名:
本校为第一且通讯机构
摘要:
The dual Z-scheme photocatalysts of beta-In2S3/g - C3N4/WO3 (ISCNWO) were synthesized with improved light adsorption, carrier separation and specific surface area for tetracycline (TC) degradation by sunlight irradiation. The ISCNWO2 exhibited superior solar photodegradation performance of TC, and the kinetic constant was 2.2, 5.6 and 2.3 times that of g-C3N4, WO3 and In2S3, respectively. According to response surface methodology, the optimum TC removal was 96.4 +/- 0.37 % at pH = 3.4 for 140 min irradiation without electrolyte. Even in river, municipal, hospital, frog farming field and tail w...

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