Bismuth tungstate (Bi2WO6) has been renowned for its affordability, non-toxic nature, and outstanding performance, but rapid carrier recombination has always been its fatal drawback. However, the inherent surface electric field of tourmaline effectively reduces carrier recombination and promotes their rapid separation. Consequently, the successful preparation of tourmaline/Bi2WO6 (T/BWO) composite materials has been achieved. Characterization and experiments indicate that, under the influence of the tourmaline electric field, the photocatalytic performance of Bi2WO6 is significantly enhanced. ...