Science and Technology Innovation Program of Hunan Province; China Postdoctoral Science Foundation [2022T150075, 2022M720541]; Hunan Provincial Department of Education Outstanding Youth Project [22B0212]; Tianjin Synthetic Biotech-nology Innovation Capacity Improvement Project [TSBI-CIP-CXRC-038]; National College Students Innovation and Entrepreneurship Training Program [S202210537024]; [2021RC2079]
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摘要:
A visible light‐driven photo oxidation‐reduction selenium amidation of selenides with isocyanides and carboxylic compounds for the synthesis of polysubstituted selenium‐containing imides is reported. The reaction involves the functionalization of Se−Se bonds under mild conditions by visible light photoredox catalysis with good tolerance of various functionalized group. A possible mechanism has been proposed.
A visible light‐driven photo oxidation‐reduction selenium amidation of selenides with isocyanides and carboxylic compounds for the s...