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Exploration of bluish violet-emitting phosphor Ca3Al4ZnO10:Ti4+ with enhanced emission by Ca2+ vacancies

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成果类型:
期刊论文
作者:
Zhou, Zhi;Zhong, Yuan;Gu, Simin;Su, Yifeng;Xia, Mao;...
通讯作者:
Zhou, Nan;Wang, Jing
作者机构:
[Xia, Mao; Zhou, Nan; Wang, Jing; Su, Yifeng; Zhang, Yongli; Zhong, Yuan; Zhou, Zhi; Gu, Simin] Hunan Agr Univ, Coll Sci, Changsha, Hunan, Peoples R China.
[Xia, Mao] Cent S Univ, State Key Lab Powder Met, Changsha, Hunan, Peoples R China.
[Wang, Jing] Sun Yat Sen Univ, Sch Chem, Sch Mat Sci & Engn, Guangzhou, Guangdong, Peoples R China.
通讯机构:
[Zhou, N; Wang, J] H
Hunan Agr Univ, Coll Sci, Changsha, Hunan, Peoples R China.
语种:
英文
关键词:
luminescence;phosphors;photoluminescence
期刊:
Journal of the American Ceramic Society
ISSN:
0002-7820
年:
2019
卷:
102
期:
4
页码:
1843-1851
基金类别:
National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21706060, 51703061]; Natural Sciences Foundation of Hunan ProvinceNatural Science Foundation of Hunan Province [2017JJ3103]; outstanding Youth Project of Hunan Education Department [17B118]
机构署名:
本校为第一且通讯机构
院系归属:
理学院
摘要:
In this paper, we introduced a bluish violet emitting phosphor Ca3Al4ZnO10:Ti (IV) (CAZO:Ti⁴⁺) synthesized by high‐temperature solid‐state reaction. Upon 265 nm excitation, a broad emission band spanned from 300 nm to 500 nm and centered at 370 nm was observed. In addition, the effects of flux and charge compensation to photoluminescence properties of CAZO:Ti⁴⁺ were systematically investigated. The results show that 103% improvement of emission intensity was achieved when 1% H3BO3 flux was introduced and 32.8% enhancement of it for 2% Ca²...

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