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Adsorption and desorption of phenylarsonic acid compounds on metal oxide and hydroxide, and clay minerals

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成果类型:
期刊论文
作者:
Xie, Xiande;Cheng, Hefa*
通讯作者:
Cheng, Hefa
作者机构:
[Xie, Xiande; Cheng, Hefa] Peking Univ, Coll Urban & Environm Sci, MOE Lab Earth Surface Proc, Beijing 100871, Peoples R China.
[Xie, Xiande] Hunan Agr Univ, Coll Resources & Environm, Changsha 410128, Peoples R China.
通讯机构:
[Cheng, Hefa] P
Peking Univ, Coll Urban & Environm Sci, MOE Lab Earth Surface Proc, Beijing 100871, Peoples R China.
语种:
英文
关键词:
Degradation;Inner-sphere complexation;Out-sphere complexation;Roxarsone;Soil mineral;p-Arsanilic acid
期刊:
Science of The Total Environment
ISSN:
0048-9697
年:
2021
卷:
757
页码:
143765
基金类别:
SEM micrographs show that α-Fe2O3, Fe(OH)3, γ-MnO2, and kaolinite all had irregular morphology, while α-FeOOH and α-Al2O3 were in needle and globular shapes, respectively (Fig. S3). The apparent particle sizes of α-Al2O3 and α-Fe2O3 were much larger than those of the other minerals (Fig. S3), which is consistent with the results of specific surface area measurements (Table 1). The BET surface areas of α-Fe2O3, α-FeOOH, Fe(OH)3, α-Al2O3, γ-MnO2, and kaolinite were determined to be 4.4, 25.9,
机构署名:
本校为其他机构
院系归属:
资源环境学院
摘要:
Adsorption and desorption of p-arsanilic add (p-ASA) and rexarsone (ROX) on six soil minerals, including hematite (alpha-Fe2O3), goethite (alpha-FeOOH), ferrihydrite (Fe(OH)(3)), aluminum oxide (alpha-Al2O3), manganese oxide (gamma-MnO2), and kaolinite, were studied, and the impact of solution matrices on their adsorption was systematically evaluated. Adsorption of p-ASA/ROX on the metal (hydro)oxide and clay minerals occurred quickly (mostly within 2 h), and could be well described by the pseudo second-order kinetic model. The apparent maximum adsorption capacities of alpha-Fe2O3, alpha-FeOOH...

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