Nickel-Catalyzed Chemoselective Asymmetric Hydrogenation of α,β-Unsaturated Ketoimines: An Efficient Approach to Chiral Allylic Amines

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成果类型：

期刊论文

作者：

Zhao, Xiang;Zhang, Feng;Liu, Kai;Zhang, Xumu;Lv, Hui*

通讯作者：

Lv, Hui

作者机构：

[Zhao, Xiang; Liu, Kai; Lv, Hui] Wuhan Univ, Minist Educ, Key Lab Biomed Polymers, Wuhan 430072, Hubei, Peoples R China.

[Zhao, Xiang; Liu, Kai; Lv, Hui] Wuhan Univ, Coll Chem & Mol Sci, Engn Res Ctr Organosilicon Cpds & Mat, Minist Educ,Sauvage Ctr Mol Sci, Wuhan 430072, Hubei, Peoples R China.

[Zhang, Feng] Hunan Agr Univ, Coll Sci, Changsha 410128, Hunan, Peoples R China.

[Lv, Hui] Chinese Acad Sci, CAS Key Lab Mol Recognit & Funct, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China.

[Zhang, Xumu] Southern Univ Sci & Technol, Shenzhen Grubbs Inst, Shenzhen 518055, Guangdong, Peoples R China.

通讯机构：

[Lv, Hui] W

[Lv, Hui] C

Wuhan Univ, Minist Educ, Key Lab Biomed Polymers, Wuhan 430072, Hubei, Peoples R China.

Wuhan Univ, Coll Chem & Mol Sci, Engn Res Ctr Organosilicon Cpds & Mat, Minist Educ,Sauvage Ctr Mol Sci, Wuhan 430072, Hubei, Peoples R China.

Chinese Acad Sci, CAS Key Lab Mol Recognit & Funct, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China.

语种：

英文

期刊：

Organic Letters

ISSN：

1523-7060

年：

2019

卷：

期：

页码：

8966-8969

DOI：

10.1021/acs.orglett.9b03365

基金类别：

National Natural Science Foundation of ChinaNational Natural Science Foundation of China [21871212, 21402145]; Natural Science Foundation of Hubei ProvinceNatural Science Foundation of Hubei Province [2018CFB430]; open foundation of CAS Key Laboratory of Molecular Recognition and Function

机构署名：

本校为其他机构

院系归属：

理学院

摘要：

An efficient synthetic route to chiral allylic amines has been developed by nickel/(S,S)-Ph-BPE complex catalyzed chemoselective asymmetric hydrogenation of alpha,beta-unsaturated ketoimines. Varieties of alpha,beta-unsaturated ketoimines have been well tolerated in this transformation to give chiral allylic amines with high yields and excellent ee values (up to 99% yield, up to 99% ee). A gram-scale reaction with 0...

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Nickel-Catalyzed Chemoselective Asymmetric Hydrogenation of α,β-Unsaturated Ketoimines: An Efficient Approach to Chiral Allylic Amines

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