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Improved luminescence and energy-transfer properties of Ca14Al10Zn6O35:Ti4+,Mn4+ deep-red-emitting phosphors with high brightness for light-emitting diode (LED) plant-growth lighting

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成果类型:
期刊论文
作者:
Zhou, Zhi;Li, Yiran;Xia, Mao*;Zhong, Yuan;Zhou, Nan*;...
通讯作者:
Xia, Mao;Zhou, Nan
作者机构:
[Xia, Mao; Zhong, Yuan; Xia, M; Zhou, Nan; Zhou, Zhi; Li, Yiran] Hunan Agr Univ, Coll Sci, Changsha 410128, Hunan, Peoples R China.
[Xia, Mao] Cent S Univ, State Key Lab Powder Met, Changsha 410083, Hunan, Peoples R China.
[Hintzen, H. T. (Bert)] Delft Univ Technol, Fac Appl Sci, Sect Fundamental Aspetts Mat & Energy, Grp Luminescent Mat, Delft, Netherlands.
通讯机构:
[Xia, M; Zhou, N] H
[Xia, Mao] C
Hunan Agr Univ, Coll Sci, Changsha 410128, Hunan, Peoples R China.
Cent S Univ, State Key Lab Powder Met, Changsha 410083, Hunan, Peoples R China.
语种:
英文
期刊:
DALTON TRANSACTIONS
ISSN:
1477-9226
年:
2018
卷:
47
期:
38
页码:
13713-13721
基金类别:
The authors would like to gratefully acknowledge research grants from National Natural Science Foundation of China (Grant No. 21706060, 51703061), Natural Sciences Foundation of Hunan Province, China (Grant No. 2016JJ3065, 2017JJ3103), National Science Foundation for Postdoctoral Scientists of China (Grant No. 2016M592427). The authors also like to thank Dequan Liu, Ronghua Wang and Huazhu Song from Pursuit LED lighting company for the help of the devices fabrication. The authors would like to thank Elsevier (webshop.else-vier.com) for the English language review.
机构署名:
本校为第一且通讯机构
院系归属:
理学院
摘要:
For plant-growth lighting, novel deep-red emission phosphors with high brightness were obtained by co-doping Ti4+ and Mn4+ into a Ca14Al10Zn6O35 substrate through a conventional solid-state reaction strategy. The nominal Ca14-(x+y)/2Al10-x-yZn6O35:xTi4+,yMn4+ (CAZO:Ti4+,Mn4+) phosphors could be excited by both near-ultraviolet (NUV) and blue-light-emitting diode (LED) chips efficiently and exhibited a strong deep-red emission band ranging from 650 nm to 750 nm, which should be the result of the 2E → 4A2 transition inside the [MnO6]8- octahedra...

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