期刊论文

Preparation of FeOOH/MnO2 and Experiment of Quick Adsorption and Removal of Low Concentration Arsenic（As） from Aqueous Solution

中文

净水技术

1009-0177

2015

5

39-43

10.3969/j.issn.1009-0177.2015.05.007

[项目名称]湖南省自然科学基金（13JJ04068）

本校为第一机构

该文用化学沉积法在纳米 MnO2表面修饰了不同量的 FeOOH，以此获得了四种 FeOOH／ MnO2材料（Fe／ Mn物质的量比分别为5／100、10／100、15／100和20／100）。通过对比，筛选出吸附效果最好的材料为20／100的 FeOOH／ MnO2，并对其进行去除水体中砷的性能研究。结果表明其吸附水中砷到达平衡时间小于10 min，速度大于单一的 MnO2和铁锰氧化合物等材料。该吸附符合 Freundlich吸附模型，最大吸附容量为19．71 mg／ g。20／100的 FeOOH／ MnO2对砷吸附的最适 pH为6且吸附率达97．4％，温度对吸附效果几乎没影响。总之，FeOOH／MnO2复合材料是一种潜在的高效去除水体中低浓度砷的材料。

4 types of FeOOH/ MnO2 ,Fe/ Mn molar ratio of which were 5 / 100,10 / 100,15 / 100 and 20 / 100,were prepared by chemical deposition. The material which had the best adsorption effect was chosen and its properties for removal of As from aqueous solution were investigated. The results show 20 / 100 FeOOH/ MnO2 has the best adsorption effect,and reaches equilibrium within 10 min,which is much faster than that of pure MnO 2 and Fe-Mn bimetal oxide. The adsorption isotherm can be described by Freundlich adsorption model,and the maximum adsorption capacity is 19. 71 mg/ g. 20 / 100 FeOOH/ MnO 2 is ...