Spectral fingerprints of DOM-tungsten interactions: Linking molecular binding to conformational changes

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作者信息关键词期刊信息基础信息归属信息摘要

成果类型：

期刊论文

作者：

Li, Weijun;Liu, Guobin;Lei, Ming;Zhou, Yaoyu;Cui, Haojie;...

通讯作者：

Du, Huihui

作者机构：

[Liu, Guobin; Zhou, Yaoyu; Li, Weijun; Lei, Ming] College of Environment & Ecology, Hunan Agricultural University, Changsha 410127, China

[Cui, Haojie] College of Resources, Hunan Agricultural University, Changsha 410127, China

[Du, Huihui] College of Environment & Ecology, Hunan Agricultural University, Changsha 410127, China. Electronic address: duhuihui@hunau.edu.cn

通讯机构：

[Du, Huihui] C

College of Environment & Ecology, Hunan Agricultural University, Changsha 410127, China. Electronic address:

语种：

英文

关键词：

Complexation;Conformation;Dissolved organic matter (DOM);Photophysical model;Tungsten

期刊：

Journal of Hazardous Materials

ISSN：

0304-3894

年：

2025

卷：

483

页码：

136649

DOI：

10.1016/j.jhazmat.2024.136649

基金类别：

CRediT Authorship Contribution Statement Weijun Li: Methodology, Software, Formal analysis, Investigation, Visualization, Writing – original draft. Guobin Liu: Investigation. Ming Lei: Supervision, Resources. Yaoyu Zhou: Supervision, Resources. Haojie Cui: Supervision. Huihui Du: Conceptualization, Visualization, Resources, Data curation, Writing – review & editing, Project administration, acquisition.

机构署名：

本校为第一且通讯机构

摘要：

Tungsten (W), a widely used yet understudied emerging contaminant, forms oxyanions in aqueous environments, distinguishing it from conventional heavy metals. While dissolved organic matter (DOM) demonstrates considerable potential for W binding, DOM-W interactions remain largely unexplored. Of particular significance, yet frequently overlooked, are the conformational changes in DOM during W binding processes. This study proposes a novel theoretical framework integrating superposition and charge transfer models to elucidate the complexity of the...

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Spectral fingerprints of DOM-tungsten interactions: Linking molecular binding to conformational changes

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