Fundamental Research Funds for the Central UniversitiesFundamental Research Funds for the Central Universities; South-Central University for Nationalities [CZR18001]; Research Foundation of Education Bureau of Hunan Province, China [86918]
机构署名:
本校为第一机构
院系归属:
资源环境学院
摘要:
A sustainable method was developed for the upgrade of biomass derived vanillin (a typical model compound of lignin) into the potential liquid biofuels over a layered double hydroxide supported Pd catalyst (abbreviated as CoAl-LDH/Pd). The CoAl-LDH/Pd catalyst showed high catalytic activity towards the hydrodeoxygenation of vanillin into 2-methoxy-4-methylphenol (MMP) under mild conditions in aqueous media. High MMP yield up to 86% was produced at 120 degrees C after 4 h. Kinetic studies revealed that the rate-determining step for the hydrodeoxygenation of vanillin was the hydrogenolysis of van...