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Bi3+ occupancy rearrangement in K2-xAxMgGeO4 phosphor to achieve ultra-broad-band white emission based on alkali metal substitution engineering

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成果类型:
期刊论文
作者:
Zhu, Haifeng;Feng, Shuqing;Kong, Zihui;Huang, Xu;Peng, Lu;...
通讯作者:
Xia, Mao(xiamao2019@hunau.edu.cn)
作者机构:
[Kong, Zihui; Xia, Mao; Feng, Shuqing; Peng, Lu; Huang, Xu; Zhu, Haifeng; Zhou, Zhi] Hunan Agr Univ, Sch Chem & Mat Sci, Changsha 410128, Peoples R China.
[Xia, Mao; Feng, Shuqing; Zhu, Haifeng; Zhou, Zhi] Hunan Opt Agr Engn Technol Res Ctr, Changsha 410128, Peoples R China.
[Wang, Jing] Sun Yat Sen Univ, Sch Chem, State Key Lab Optoelect Mat & Technol, Guangzhou 510275, Peoples R China.
[Wang, Jing] Sun Yat Sen Univ, Sch Mat Sci & Engn, Guangzhou 510275, Peoples R China.
[Wong, Wai-Yeung] Hong Kong Polytech Univ, Dept Appl Biol & Chem Technol, Hong Kong, Peoples R China.
通讯机构:
[Mao Xia] S
School of Chemistry and Materials Science, Hunan Agricultural University, Changsha 410128, PR China<&wdkj&>Hunan Optical Agriculture Engineering Technology Research Center, Changsha 410128, PR China
语种:
英文
关键词:
K2MgGeO4:Bi3+;Phosphor;Substitution engineering;Tunable emission;Ultra-broad-band white emission;WLED
期刊:
Applied Surface Science
ISSN:
0169-4332
年:
2021
卷:
563
页码:
150252
基金类别:
The authors would like to gratefully acknowledge funds from the National Natural Science Foundation of China (Grant No. 21706060 , 51703061 , 51974123 ), the Hunan provincial Engineering Technology Research Center for Optical Agriculture (Grant No. 2018TP2003), the Scientific Research Fund of Hunan Provincial Education Department (19C0903), the Distinguished Youth Foundation of Hunan Province (Grant No. 2020JJ2018) and the Natural Sciences Foundation of Hunan agricultural university, China (Grant No. 19QN11). W.-Y. Wong acknowledges the financial support from the Hong Kong Research Grants Council (C4006-17G and PolyU 153058/19P), the Hong Kong Polytechnic University ( 1-ZE1C ) and Ms Clarea Au for the Endowed Professorship in Energy (847S).
机构署名:
本校为第一机构
摘要:
Ultra-broad-band white emitting phosphors have a wide application prospect in the new generation of illumination systems. Due to the sensitivity of Bi3+ to the surrounding environment, it exhibits different luminescence properties in different crystallographic sites, which makes it easy to achieve white emission. Cationic substitution engineering is the most effective strategy for controlling the environment around Bi-site and realizing the spectrum tuning. Herein, we conducted substitution engineering in K2MgGeO4:Bi3+ (KMGO:Bi3+) that uses alk...

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