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Efficient Oxidative Dehydrogenation of N-Heterocycles over Nitrogen-Doped Carbon-Supported Cobalt Nanoparticles

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成果类型:
期刊论文
作者:
Liao, Chanjuan;Li, Xun;Yao, Kaiyue;Yuan, Ziliang;Chi, Quan;...
通讯作者:
Zhang, Zehui
作者机构:
[Liao, Chanjuan] Hunan Agr Univ, Coll Resources & Environm, Nongda Rd 1, Changsha 410128, Hunan, Peoples R China.
[Yao, Kaiyue; Li, Xun; Zhang, Zehui; Chi, Quan; Yuan, Ziliang] South Cent Univ Nationalities, Key Lab Catalysis & Mat Sci, Minist Educ, Minyuan Rd 182, Wuhan 430074, Hubei, Peoples R China.
通讯机构:
[Zhang, Zehui] S
South Cent Univ Nationalities, Key Lab Catalysis & Mat Sci, Minist Educ, Minyuan Rd 182, Wuhan 430074, Hubei, Peoples R China.
语种:
英文
关键词:
Oxidative dehydrogenation;N-Heterocyclic compounds;Heteroarenes;Nitrogen-doped carbon materials;Cobalt nanoparticles
期刊:
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
ISSN:
2168-0485
年:
2019
卷:
7
期:
16
页码:
13646-13654
基金类别:
Special Fund for Basic Scientific Research of Central Colleges, South-Central University for Nationalities [CZZ 19002]; National Natural Science Fundation of Hunan Province [2018jj3244]; National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [2182175]
机构署名:
本校为第一机构
院系归属:
资源环境学院
摘要:
Catalytic oxidative dehydrogenation of N-heterocyclic compounds has been considered to be an important route to access heteroarenes. In this study, a heterogeneous catalyst by the loading of cobalt nanoparticles on the nitrogen-doped carbon support (Co/MC) was prepared and studied for the oxidation of N-heterocyclic compounds with O2. A variety of reaction parameters were optimized for this transformation, and quinolines with yields from 84.9% to 98.8% were achieved by the oxidation of N-heterocycles at 150 °C under 2.5 bar O2. The oxidation o...

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