Special Fund for Basic Scientific Research of Central Colleges, South-Central University for Nationalities [CZZ 19002]; National Natural Science Fundation of Hunan Province [2018jj3244]; National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [2182175]
机构署名:
本校为第一机构
院系归属:
资源环境学院
摘要:
Catalytic oxidative dehydrogenation of N-heterocyclic compounds has been considered to be an important route to access heteroarenes. In this study, a heterogeneous catalyst by the loading of cobalt nanoparticles on the nitrogen-doped carbon support (Co/MC) was prepared and studied for the oxidation of N-heterocyclic compounds with O2. A variety of reaction parameters were optimized for this transformation, and quinolines with yields from 84.9% to 98.8% were achieved by the oxidation of N-heterocycles at 150 °C under 2.5 bar O2. The oxidation o...