Electrochemically promoted oxidative α-cyanation of tertiary and secondary amines using cheap AIBN

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期刊论文

作者：

Gui, Qing-Wen;Xiong, Zhi-Yuan;Teng, Fan;Cai, Tian-Cheng;Li, Qiang;...

通讯作者：

Qing-Wen Gui<&wdkj&>Qiang Li<&wdkj&>Xiaoying Liu

作者机构：

[Li, Qiang; Teng, Fan; Liu, Xiaoying; Hu, Wenxia; Gui, Qing-Wen; Yu, Jialing; Cai, Tian-Cheng; Wang, Xiaoli; Xiong, Zhi-Yuan] Hunan Agr Univ, Coll Chem & Mat Sci, Changsha 410128, Peoples R China.

[Gui, Qing-Wen] Hunan Univ, Coll Chem & Chem Engn, State Key Lab Chemo Biosensing & Chemometr, Changsha 410082, Peoples R China.

[Li, Qiang] Hunan Agr Univ, Coll Agron, Changsha 410128, Peoples R China.

通讯机构：

[Qing-Wen Gui; Qiang Li; Xiaoying Liu] C

College of Chemistry and Materials Science, Hunan Agricultural University, Changsha 410128, People's Republic of China<&wdkj&>College of Agronomy, Hunan Agricultural University, Changsha 410128, People's Republic of China<&wdkj&>College of Chemistry and Materials Science, Hunan Agricultural University, Changsha 410128, People's Republic of China<&wdkj&>College of Chemistry and Materials Science, Hunan Agricultural University, Changsha 410128, People's Republic of China<&wdkj&>State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, People's Republic of China

语种：

英文

期刊：

Organic & Biomolecular Chemistry

ISSN：

1477-0520

年：

2021

卷：

期：

页码：

8254-8258

DOI：

10.1039/d1ob01416a

基金类别：

Natural Science Foundation of Hunan Province, ChinaNatural Science Foundation of Hunan Province [2020JJ4035]; Hunan Province Science Foundation for Youths [2018JJ3215]; Double First-Class Construction Project of Hunan Agricultural University [SYL2019064, SYL2019063]; Basic Research Foundation of China Tobacco Yunnan Industrial Corporation [11700167]; Foundation of Hunan Provincial Key Laboratory of Crop Germplasm Innovation and Resource Utilization [18KFXM07]

机构署名：

本校为第一机构

院系归属：

农学院

摘要：

The electrochemical α-cyanation of tertiary and secondary amines has been developed by using a cheap cyanide reagent, azobisisobutyronitrile (AIBN). The CN radical, generated through n-Bu4NBr-meidated electrochemical oxidation, participates in a novel α-cyanation reaction ...

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Electrochemically promoted oxidative α-cyanation of tertiary and secondary amines using cheap AIBN

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