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Catalytic co-pyrolysis of tobacco stem and polypropylene over Ni/CaO-Al2O3: synergistic production and distribution of pyrolysis oil, pyrolysis gas and carbon nanotubes

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成果类型:
期刊论文
作者:
Tang, Xin;Yang, Jia Yi;Heluo, Yu Yang;Li, Xiang Yang;Dong, Hang;...
通讯作者:
Zhou, Zhi;Luo, W
作者机构:
[Tang, Xin; Dong, Hang; Zhou, Zhi; Li, Xiang Yang] Hunan Agr Univ, Sch Chem & Mat Sci, Changsha 410128, Peoples R China.
[Heluo, Yu Yang; Yang, Jia Yi; Luo, Wei] Hunan Agr Univ, Coll Agron, Changsha 410128, Peoples R China.
[Heluo, Yu Yang; Tang, Xin; Dong, Hang; Luo, Wei; Yang, Jia Yi; Zhou, Zhi; Li, Xiang Yang] Hunan Engn Res Ctr Biochar, Changsha 410128, Peoples R China.
通讯机构:
[Luo, W ; Zhou, Z] H
Hunan Engn Res Ctr Biochar, Changsha 410128, Peoples R China.
语种:
英文
关键词:
CaO;Catalytic co-pyrolysis;Pyrolysis oil;Pyrolysis gas;Carbon nanotubes
期刊:
Fuel
ISSN:
0016-2361
年:
2025
卷:
387
页码:
134354
基金类别:
National Natural Science Foundation of China [51974123]; Distinguished Youth Foundation of Hunan Province [2022JJ10030]; Natural Science Foundation of Hunan Province, China [2021JJ40261]; Earmarked fund for China Agriculture Research System [CARS-01-27]; science and technology innovation Program of Hunan Province [2022WZ1022]; The 2022 National Center of Technology Innovation for Saline-Alkali Tolerant Rice functional improvement project [2022PT1005]; Study and demonstration of tobacco field waste Resource utilization in Hengyang Area [HYYC2023KJ31]; Study and application of nitrogen controlled release for tobacco based on porous adsorption and novel coating [CS2022KJ01]; Hunan Engineering Research Center for Biochar, Hunan Optical Agriculture Engineering Technology Research Center [2018TP2003]; [2023JJ40307]
机构署名:
本校为第一机构
院系归属:
农学院
摘要:
Inexpensive metal oxides are the promising catalyst supports for catalytic pyrolysis to produce pyrolysis oil, pyrolysis gas and carbon nanotubes (CNTs). The catalytic co-pyrolysis of tobacco stem (TS) and recycled plastic (PP) is conducted using a Ni/CaO-Al 2 O 3 catalyst with varying CaO/Al 2 O 3 ratios (1:0, 3:1, 1:1, 1:3 and 0:1) in a two-stage fixed bed reactor. Subsequently, TS and PP were decomposed at high temperature to produce pyrolysis oil and H 2 -rich pyrolysis gas, while CNTs were synthesized using chemical vapor deposition (CVD) ...

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