Tungsten (W) is an emerging contaminant whose environmental behaviors remain rather sketchy, narrow, and fragmentary. The mobility and fate of W in the aquatic environments may be influenced by naturally dissolved organic matter (DOM), nevertheless, no studies have addressed how W is bound to DOM. In this study, complexation behaviors and mechanisms of W(VI) with representative DOM, humic acid (HA) and fulvic acid (FA), were examined by batch adsorption, spectrometry, and isothermal titration calorimetry (ITC) under environmentally-relevant con...