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Activation of persulfate with dual-doped reduced graphene oxide for degradation of alkylphenols

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成果类型:
期刊论文
作者:
Wang, Qiang;Li, Lei;Luo, Li;Yang, Yuan*;Yang, Zhaoguang*;...
通讯作者:
Yang, Zhaoguang;Yang, Yuan
作者机构:
[Luo, Li; Li, Haipu; Wang, Qiang; Li, Lei; Yang, Zhaoguang] Cent South Univ, Key Lab Hunan Prov Water Environm & Agr Prod Safe, Coll Chem & Chem Engn, Changsha, Hunan, Peoples R China.
[Yang, Yuan; Zhou, Yaoyu] Hunan Agr Univ, Coll Resources & Environm, Int Joint Lab Hunan Agr Typ Pollut Restorat & Wat, Changsha, Hunan, Peoples R China.
通讯机构:
[Yang, Zhaoguang] C
[Yang, Yuan] H
Cent South Univ, Key Lab Hunan Prov Water Environm & Agr Prod Safe, Coll Chem & Chem Engn, Changsha, Hunan, Peoples R China.
Hunan Agr Univ, Coll Resources & Environm, Int Joint Lab Hunan Agr Typ Pollut Restorat & Wat, Changsha, Hunan, Peoples R China.
语种:
英文
关键词:
Activation of persulfate;Catalytic oxidation;Degradation of alkylphenols;Dual-doped reduced graphene oxide;Reactive radicals
期刊:
Chemical Engineering Journal
ISSN:
1385-8947
年:
2019
卷:
376
页码:
120891
基金类别:
This study was financially supported by the National Natural Science Foundation of China [Grant No. 21407182 and 51709103 ], Natural Science Foundation of Hunan Province of China [Grant No. 2018jj2490 ], Special Fund for Agro-scientific Research in the Public Interest of China [Grant No. 201503108 ], National Key R&D Projects of China [Grant No. 2016YFC0403002 ], Science & Technology Innovation Platform and Talent Project of Hunan Province of China [Grant No. 2018WK4007 ] and Double first-class construction project of Hunan Agricultural University [Grant No. SYL201802005 ].
机构署名:
本校为通讯机构
院系归属:
资源环境学院
摘要:
In this study, the nitrogen and sulfur dual doped reduced graphene oxide (N,S-rGO) were synthesized using thermal decomposition strategy. And the prepared N,S-rGO could efficiently activate persulfate (PS) to generate reactive radicals for the catalytic degradation of alkylphenols at environmentally relevant concentration. The hydroxyl radicals ([rad]OH) and sulfate radicals (SO4[rad]−) generated by PS activation were analyzed by electron paramagnetic resonance (EPR). The used N,S-rGO (50 mg/L) and potassium persulfate (0.9 mmol/L) achieved co...

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