Bronsted acid-promoted thiazole synthesis under metal-free conditions using sulfur powder as the sulfur source

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成果类型：

期刊论文

作者：

Ni, Penghui;Tan, Jing;Li, Rong;Huang, Huawen;Zhang, Feng*;...

通讯作者：

Deng, Guo-Jun;Zhang, Feng

作者机构：

[Li, Rong; Tan, Jing; Deng, Guo-Jun; Huang, Huawen; Ni, Penghui] Xiangtan Univ, Key Lab Green Organ Synth & Applicat Hunan Prov, Key Lab Environm Friendly Chem & Applicat, Minist Educ,Coll Chem, Xiangtan 411105, Peoples R China.

[Zhang, Feng] Hunan Agr Univ, Coll Sci, Changsha 410128, Peoples R China.

通讯机构：

[Deng, Guo-Jun] X

[Zhang, Feng] H

Xiangtan Univ, Key Lab Green Organ Synth & Applicat Hunan Prov, Key Lab Environm Friendly Chem & Applicat, Minist Educ,Coll Chem, Xiangtan 411105, Peoples R China.

Hunan Agr Univ, Coll Sci, Changsha 410128, Peoples R China.

语种：

英文

期刊：

RSC Advances

ISSN：

2046-2069

年：

2020

卷：

期：

页码：

3931-3935

DOI：

10.1039/c9ra09656f

基金类别：

National Natural Science Foundation of ChinaNational Natural Science Foundation of China [21871226, 21572194]; China Postdoctoral Science FoundationChina Postdoctoral Science Foundation [2018M632976, 2019T120709]; Hunan Provincial Innovative Foundation for Postgraduate [CX2018B362, CX2018B046]

机构署名：

本校为通讯机构

院系归属：

理学院

摘要：

A Bronsted acid-promoted sulfuration/annulation reaction for the one-pot synthesis of bis-substituted thiazoles from benzylamines, acetophenones, and sulfur powder has been developed. One C-N bond and multi C-S bonds were selectively formed in one pot. The choice of the Bronsted acid was the key to the high efficiency of this tra...

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Bronsted acid-promoted thiazole synthesis under metal-free conditions using sulfur powder as the sulfur source

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