Dissolved organic matter (DOM) can clearly reflect composting components changes, thus it is supposed to indicate the humification process during composting. To demonstrate this, three compost mixtures and two techniques were arranged. DOM evolution was detected by three spectral techniques. X-ray diffraction (XRD) showed that the crystal structure substances decreased gradually during the composting, including cellulose, struvite, sylvine, quartz, and calcite; Specifically, the struvite was found, which was conducive to the fixation of nitrogen and phosphorus. Fourier transform infrared spect...