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A novel Bi2S3 nanowire @ TiO2 nanorod heterogeneous nanostructure for photoelectrochemical hydrogen generation

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成果类型:
期刊论文
作者:
Liu, Canjun;Yang, Yahui;Li, Wenzhang*;Li, Jie*;Li, Yaomin;...
通讯作者:
Li, Wenzhang;Li, Jie
作者机构:
[Li, Jie; Liu, Canjun; Li, Wenzhang; Chen, Qiyuan] Cent S Univ, Sch Chem & Chem Engn, Changsha 410083, Hunan, Peoples R China.
[Li, Jie; Liu, Canjun; Li, Wenzhang; Chen, Qiyuan] Key Lab Hunan Prov Met & Mat Proc Rare Met, Changsha 410083, Hunan, Peoples R China.
[Yang, Yahui] Hunan Agr Univ, Coll Resources & Environm, Changsha 410128, Hunan, Peoples R China.
[Li, Yaomin] UCL, Dept Chem, 20 Gordon St, London WC1H 0AJ, England.
通讯机构:
[Li, WZ; Li, J] C
Cent S Univ, Sch Chem & Chem Engn, Changsha 410083, Hunan, Peoples R China.
语种:
英文
关键词:
Bi2S3 nanowire;Heterogeneous nanostructure;Hydrogen generation;Photoelectrochemical;TiO2 nanorod
期刊:
Chemical Engineering Journal
ISSN:
1385-8947
年:
2016
卷:
302
页码:
717-724
基金类别:
The depiction of the preparation process of Bi2S3 NWs/TiO2 NRs and SEM images of samples for each step are shown in Figs. 1 and 2, respectively. First, TiO2 NRs directly grown on FTO substrates were obtained via a simple hydrothermal process. The SEM images of TiO2 NRs shown in Fig. 2a, b reveal that TiO2 NRs are smooth and their average length is about 1.5 μm. Second, the BiVO4 layer was covered on the surface of TiO2 NRs by a simply soaking and annealing treatment process. As shown in Fig. 2
机构署名:
本校为其他机构
院系归属:
资源环境学院
摘要:
In this paper, we demonstrate a novel heterogeneous nanostructure by grafting the Bi2S3 nanowires (NWs) on TiO2 nanorod arrays (NRs) and the prepared films as photoanodes show an excellent photoelectrochemical (PEC) hydrogen generation performance. The hydrogen evolution rate is 35.97 μmol cm-2 h-1 at a potential of 0.676 V vs. RHE (-0.2 V vs. Ag/AgCl) under visible light illumination. Importantly, the growth mechanism of such a heterogeneous nanostructure is put forward firstly and the intrinsic nature of Bi2S3 crystal structure is the main r...

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