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Enhancing the electrochemical properties of LiTi2(PO4)3/C anode for aqueous rechargeable lithium battery by Li vacancy

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成果类型:
期刊论文
作者:
Zhou, Zhi;Li, Yiran;Xia, Mao*;Zhou, Nan
通讯作者:
Xia, Mao
作者机构:
[Xia, Mao; Zhou, Zhi; Zhou, Nan; Li, Yiran] Hunan Agr Univ, Coll Sci, Changsha 410128, Hunan, Peoples R China.
[Xia, Mao] Cent S Univ, State Key Lab Powder Met, Changsha 410083, Hunan, Peoples R China.
通讯机构:
[Xia, Mao] H
Hunan Agr Univ, Coll Sci, Changsha 410128, Hunan, Peoples R China.
语种:
英文
关键词:
Aqueous rechargeable lithium battery;Electrochemical kinetics;Energy storage;Li vacancy;LiTi 2 (PO 4 ) 3 /C composite
期刊:
Solid State Ionics
ISSN:
0167-2738
年:
2018
卷:
315
页码:
1-6
基金类别:
Natural Sciences Foundation of Hunan Province, China [2016JJ3065, 2017JJ3103]; National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21706060, 51703061]; National Science Foundation for Postdoctoral Scientists of ChinaChina Postdoctoral Science FoundationNational Natural Science Foundation of China (NSFC) [2016M592427]; Research Foundation of Hunan Agricultural University [13YJ02, 14YJ05]; Hunan Provincial Key Laboratory for Germplasm Innovation and Utilization of Crop [15KFXM06, 15KFXM20]
机构署名:
本校为第一且通讯机构
院系归属:
理学院
摘要:
In this paper, Li1–xTi2(PO4)3/C composites (x = 0, 0.03, 0.05, 0.07) were synthesized by sol-gel approach, and the influence of Li vacancy on electrochemical performance of LiTi2(PO4)3/C anode for aqueous rechargeable lithium battery was studied. Li vacancy hardly influences the crystal structure and morphology of the composite. Electrochemical measurement results demonstrated that Li1–xTi2(PO4)3/C exhibited better performance compared with pristine LiTi2(PO4)3/C, and Li0.95Ti2(PO4)3/C has the best properties. Li0.95Ti2(PO4)3/C delivered the discharge capacity of 104.3, 92.6, and 7...

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