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Enhancing the electrochemical performance of micron-scale SiO@C/CNTs anode via adding piezoelectric material BaTiO3 for high-power lithium ion battery

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成果类型:
期刊论文
作者:
Mao Xia;Li Yi-ran;Xiang Xiong;Wang Hu;Tang, Yi-wei;...
通讯作者:
Zhi Zhou;Zhang, Hong-bo
作者机构:
[Nan Zhou; Li Yi-ran; Zhi Zhou; Tang, Yi-wei; Mao Xia] Hunan Agr Univ, Coll Sci, Hunan Prov Engn Technol Res Ctr Opt Agr, 1 Nongda Rd, Changsha 410128, Hunan, Peoples R China.
[Xiang Xiong; Mao Xia; Wang Hu; Zhang, Hong-bo] Cent S Univ, State Key Lab Powder Met, Changsha 410083, Hunan, Peoples R China.
通讯机构:
[Zhi Zhou] H
[Zhang, Hong-bo] C
Hunan Agr Univ, Coll Sci, Hunan Prov Engn Technol Res Ctr Opt Agr, 1 Nongda Rd, Changsha 410128, Hunan, Peoples R China.
Cent S Univ, State Key Lab Powder Met, Changsha 410083, Hunan, Peoples R China.
语种:
英文
关键词:
Li-ion mobility;Piezoelectric material BaTiO3;Local electric potential;Silicon monoxide anode;Large volume expansion
期刊:
Journal of Alloys and Compounds
ISSN:
0925-8388
年:
2019
卷:
800
页码:
116-124
基金类别:
National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21706060, 51703061]; Natural Sciences Foundation of Hunan Province, China [2017JJ3103]; Outstanding Youth Project of Hunan Education Department [17B118]; Hunan Provincial Engineering Technology Research Center for Optical Agricultural [2018TP2003]
机构署名:
本校为第一且通讯机构
院系归属:
理学院
摘要:
Silicon monoxide (SiO)-based negative materials have attracted widespread attention due to the low working potential and high specific capacity. However, the large volume dilation (about 200%) is adverse to the electrochemical performance of battery during the charge-discharge process. To overcome the disadvantage of volume change, much effort has been paid to minimize the volume expansion. Unfortunately, the volume change is inescapable no matter how to modify the SiO-based materials. Therefore, utilizing the characteristics of volume expansion to improve the electrochemical properties of SiO...

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