期刊论文

Zhi Zhou;Zhang, Hong-bo

英文

Journal of Alloys and Compounds

0925-8388

2019

800

116-124

10.1016/j.jallcom.2019.05.365

The authors would like to gratefully acknowledge research grants from National Natural Science Foundation of China (Grant No. 21706060 , 51703061 ), Natural Sciences Foundation of Hunan Province, China (Grant No. 2017JJ3103 ), the Outstanding Youth Project of Hunan Education Department (Grant No. 17B118 ) and Hunan Provincial Engineering Technology Research Center for Optical Agricultural (Grant No. 2018TP2003 ).

本校为第一且通讯机构

Silicon monoxide (SiO)-based negative materials have attracted widespread attention due to the low working potential and high specific capacity. However, the large volume dilation (about 200%) is adverse to the electrochemical performance of battery during the charge-discharge process. To overcome the disadvantage of volume change, much effort has been paid to minimize the volume expansion. Unfortunately, the volume change is inescapable no matter how to modify the SiO-based materials. Therefore, utilizing the characteristics of volume expansio...