K3PO4-promoted domino reactions: diastereoselective synthesis of trans-2,3-dihydrobenzofurans from salicyl N-tert-butanesulfinyl imines and sulfur ylides

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作者信息关键词期刊信息基础信息归属信息摘要

成果类型：

期刊论文

作者：

Zhang, Minxuan;Lu, Tianyu;Zhao, Yun;Xie, Guixian*;Miao, Zhiwei*

通讯作者：

Miao, Zhiwei;Xie, Guixian

作者机构：

[Lu, Tianyu; Miao, Zhiwei; Zhao, Yun; Zhang, Minxuan] Nankai Univ, Coll Chem, State Key Lab, Weijin Rd 94, Tianjin 300071, Peoples R China.

[Lu, Tianyu; Miao, Zhiwei; Zhao, Yun; Zhang, Minxuan] Nankai Univ, Coll Chem, Inst Elementoorgan Chem, Weijin Rd 94, Tianjin 300071, Peoples R China.

[Miao, Zhiwei] Collaborat Innovat Ctr Chem Sci & Engn Tianjin, Tianjin 300071, Peoples R China.

[Xie, Guixian] Hunan Agr Univ, Coll Resources & Environm, Changsha 410128, Hunan, Peoples R China.

通讯机构：

[Miao, Zhiwei] N

[Miao, Zhiwei] C

[Xie, Guixian] H

Nankai Univ, Coll Chem, State Key Lab, Weijin Rd 94, Tianjin 300071, Peoples R China.

Nankai Univ, Coll Chem, Inst Elementoorgan Chem, Weijin Rd 94, Tianjin 300071, Peoples R China.

语种：

英文

期刊：

RSC Advances

ISSN：

2046-2069

年：

2019

卷：

期：

页码：

11978-11985

DOI：

10.1039/c9ra00309f

基金类别：

National Key Research and Development Program of China [2016YFD0201200]; Rural Affairs Commission of the CPC Tianjin Municipal Committee [2016D01A016]; Key Technologies R & D Program of Tianjin [17YFZCGX00470]

机构署名：

本校为通讯机构

院系归属：

资源环境学院

摘要：

An efficient domino annulation between sulfur ylides and salicyl N-tert-butylsulfinyl imines was developed. The reaction proceeds with a diastereodivergent process, the configuration of the sulfinyl group determining the stereochemical course of the reaction. The method allows the synthesis of a highly substituted trans-2,3-dihydrobenzofuran skeleton with hi...

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K3PO4-promoted domino reactions: diastereoselective synthesis of trans-2,3-dihydrobenzofurans from salicyl N-tert-butanesulfinyl imines and sulfur ylides

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