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One-step synthesis of nanoporous silicon @ graphitized carbon composite and its superior lithium storage properties

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成果类型:
期刊论文
作者:
Wang, Zhiguo;Zheng, Biao;Liu, Hui;Zhang, Chun;Wu, Fangfang;...
通讯作者:
Yu, Peng
作者机构:
[Luo, Huayun; Yu, Peng; Wang, Zhiguo; Zhang, Chun; Liu, Hui; Wu, Fangfang; Zheng, Biao] Hunan Agr Univ, Sch Chem & Mat Sci, Changsha 410128, Peoples R China.
通讯机构:
[Yu, Peng] H
Hunan Agr Univ, Sch Chem & Mat Sci, Changsha 410128, Peoples R China.
语种:
英文
关键词:
Lithium ion batteries;Anode materials;Silicon/carbon composites;Graphitized carbon;Magnesiothermic reduction
期刊:
Journal of Alloys and Compounds
ISSN:
0925-8388
年:
2021
卷:
861
页码:
157955
基金类别:
National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [51801065]; National College Students Innovation and Entrepreneurship Training Program [201910537010]; Natural Science Foundation of Hunan ProvinceNatural Science Foundation of Hunan Province [2019JJ50252]; Scientific Research Foundation of Hunan Provincial Education DepartmentHunan Provincial Education Department [19C0900]
机构署名:
本校为第一且通讯机构
摘要:
Nanoporous silicon @ graphitized carbon (NPSi@C) composites have been reasonably designed and synthesized via one-step magnesiothermic co-reduction using rice husks as the silicon source and CO2 as the carbon source. In the self-assembly process, the nano-silicon prepared from rice husk-derived SiO2 is made into a porous structure and uniformly recombined with graphitized carbon formed by CO2 reduction at low temperature (680 degrees C). The nanoporous structure has contributed to accommodate the large volume effect of activated silicon and provides sufficient channels for the transfer of lith...

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