In this paper, the N and P co-doped reduce graphene oxide (N, P-rGO) was prepared with one-pot solution method and characterized by using SEM and electrochemical technology. It was found that the N, P-rGO has an outstanding conductivity, large surface area and excellent electrocatalytic activity to hydroquinone (HQ) and catechol (CC), which usually coexist in aqueous environment. Under the optimal conditions, compared with bare glassy carbon electrode (GCE) and N doped reduce graphene oxide (N-rGO) modified GCE (N-rGO/GCE), the N, P-rGO/GCE displayed an excellent simultaneous determination tow...