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Engineering Janus Interfaces of Ceramic Electrolyte via Distinct Functional Polymers for Stable High-Voltage Li-Metal Batteries

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成果类型:
期刊论文
作者:
Liang, Jia-Yan;Zeng, Xian-Xiang;Zhang, Xu-Dong;Zuo, Tong-Tong;Yan, Min;...
通讯作者:
Guo, Yu-Guo;Wan, Li-Jun
作者机构:
[Zuo, Tong-Tong; Shi, Ji-Lei; Zhang, Xu-Dong; Wan, Li-Jun; Guo, Yu-Guo; Yan, Min; Yin, Ya-Xia; Liang, Jia-Yan] Chinese Acad Sci, Key Lab Mol Nanostruct & Nanotechnol, Res Educ Ctr Excellence Mol Sci, BNLMS,Inst Chem, Beijing 100190, Peoples R China.
[Wu, Xiong-Wei; Zeng, Xian-Xiang] Hunan Agr Univ, Coll Sci, Changsha 410128, Hunan, Peoples R China.
[Zuo, Tong-Tong; Wan, Li-Jun; Guo, Yu-Guo; Yin, Ya-Xia; Liang, Jia-Yan] Univ Chinese Acad Sci, Beijing 100049, Peoples R China.
通讯机构:
[Guo, YG; Wan, LJ] C
[Guo, YG; Wan, LJ] U
Chinese Acad Sci, Key Lab Mol Nanostruct & Nanotechnol, Res Educ Ctr Excellence Mol Sci, BNLMS,Inst Chem, Beijing 100190, Peoples R China.
Univ Chinese Acad Sci, Beijing 100049, Peoples R China.
语种:
英文
期刊:
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
ISSN:
0002-7863
年:
2019
卷:
141
期:
23
页码:
9165-9169
基金类别:
This work was supported by the Basic Science Center Project of Natural Science Foundation of China under grant no. 51788104, the National Key R&D Program of China (grant no. 2016YFA0202500), the National Natural Science Foundation of China (grant no. 21773264), the Beijing Natural Science Foundation (L172023), and the “Transformational Technologies for Clean Energy and Demonstration”, Strategic Priority Research Program of the Chinese Academy of Sciences (grant no. XDA21070300). Ji-Lei Shi thanks the financial support from the Youth Innovation Promotion Association CAS (grant no. 2019033).
机构署名:
本校为其他机构
院系归属:
理学院
摘要:
The fast-ionic-conducting ceramic electrolyte is promising for next-generation high-energy-density Li-metal batteries, yet its application suffers from the high interfacial resistance and poor interfacial stability. In this study, the compatible solid-state electrolyte was designed by coating Li1.4Al0.4Ti1.6(PO4)3 (LATP) with polyacrylonitrile (PAN) and polyethylene oxide (PEO) oppositely to satisfy deliberately the disparate interface demands. Wherein, the upper PAN constructs soft-contact with LiNi0.6Mn0.2Co0.2O2, and the lower PEO protects L...

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