The plasticity and α→ω transformation are important for the toughness and ductility of hcp titanium under shock loading. However, three questions remain outstanding: (i) what mechanisms govern the plasticity and transformation, (ii) how does the microstructure, i.e., grain boundaries (GBs) and crystallographic orientations, affect them, and (iii) does the transformation take place dependent on the plasticity, such as dislocation slips? We conduct large-scale nonequilibrium molecular dynamics simulations to study shock-induced plasticity and ...